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Self explanatory. My lists in order:

Most evil
The Joker
Lex Luthor
Darkseid
The Scarecrow
Metallo

Least evil
The Hulk (considered a villain)
Dr. Octopus
Mystique
Magneto
Pyro

Most Evil:
Carnage
Doomsday
Mr.Sinister
Joker
Dr.Doom

Least Evil:
Vulture
Toyman
Juggernaut
Penguin
Toad

Most evil:

Carnage

Least evil

Vulture

Most Evil:
Spiderman
Red Skull
Darkseid
Carnage
Sinister
Apoc

Least Evil:
Hal Jordan
Lex Luthor
Hulk
Namor
Cable
Silver Surfer

Most evil: Thanos.

Least: Magneto.

-AC

Most evil: Apocalypse
Least evil:Magneto

Most evil:
Joker (but is he evil or plain crazy!)
Carnage
Dr Light (before his ("lobotomy"

Least evil:
Magneto (think malcolm x)
Sandman (just easily confused)
Venom