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Here's my list:

Batman (costume from Begins)
Spawn
Two-Face
Catwoman (Batman Returns)
Nightwing
The Flash
Venom
Nightcrawler
Superman

Probably White Tiger (Kasper Cole) or Night Raven. Something about that noir type trench coat just works.

Gambit
Silver Sable
Dark Phoenix
Carnage
Venom
Scarlet Spider
The Lizard
Mysterio
The Scarecrow
Ultron

Punisher
Ghost Rider
Carnage

Onslaught
Gambit (X-treme costume)
Venom
Psylocke (hot stuff)
Dark Phoenix
Nightwing/Deadpool/Spider-man

ironman

thor

eradicator *******

venom

spiderman with symbiote

lasher

ghost rider

captain america

thanos

onslaught

apocolypse

son of darkseid superman

Psylocke & Elektra psylocke elektra

and maybe Thor....

Ghost Rider, Deadpool, Certain versions of Thor, Surfer, Iron-Man now and then.

-AC

Batman
Venom
Phsylocke
Pheonix

I think storm and emma look cool

Batman (black costume=instant coolness)
Wolverine (he is just simply awesome looking)
Silver Surfer (sleek and alien-like...so he looks nifty)
Punisher (skull costume, with guns all over)
Venom and Carnage because the symbiotes are very cool