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Which villain?

Ultron, superior punching power and endurance, more intelligent, more dangerous and probably with much better feats and overall character development

How does he have better endurance?

He is indestructible and cannot get tired.

I don't think Brimstone ever got tired. He's not even truly living. He's even fought inside the sun before.

Has he been hurted? I suppose he has no brain.

Ultron.