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In Winter Soldier, Rumlow was last man to get knocked out in the elevator fight and he was beating Falcon's ass at the movie's climax. How would he fair h2h against Black Widow?

I say Rumlow. Call me sexist, but I still believe a skilled, bigger male fighter beats a skilled, smaller female fighter any day.

Widow did get the best of Hawkeye though.

hawkeye is more a sharpshooter, never a h2h dude

Widow stood up against WS, she face palms Brock.

Rumlow couldn't take out Falcon in their H2H in the few mins they fought.

Widow handled herself against The Winter Soldier and has shown super-human levels at times. eg jumping off Cap and single arm grabbing the Chitauri speeder.

Widow kicks his ass 10/10

Did you guys watch Cap 2, she held her own against Winter Soldier slightly better than Loki did vs Hulk. Slightly.

That said Brock didn't do enough to say he is on her level, though he was obviously beating Falcon.