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Buggy The Clown vs Green Goblin

Captain Kuro vs Kraven The Hunter

Don Krieg vs Scorpion

Arlong vs The Lizard

Mr.1 vs Tombstone

Sir Crocodile vs Sandman

God Eneru vs Electro

Aokiji vs Hydroman

Rob Lucci vs Doc Ock

Gecko Moria vs Morbius The Vampire

Akainu vs Molten Man

Jesus Burgess vs Rhino

Blackbeard(Pre Gura Gura) vs Venom

Donquixote Doflamingo vs Carnage

Shichibukai(Blackbeard is not included) vs Sinister 6(All members)

.Pre-Timeskip version of OP villains vs Some of Spidey's rogue members.

.No Prep,BFR,TP everyone has basic knowledge about each other.

.If some fights are too onesided, give these characters a month of prep,full knowledge of his opponent, best weapons or use their strongest versions.

.Win by death or K.O.

.Round 1: The fight takes place in Los Angeles(no population).

.Round 2: The fight takes place in an Amazonian Rainforest Jungle.

.Bonus: How Spidey would rank in OPverse.

In general, One Piece villains slaughter due to very high toughness, strength, and speed.

Buggy vs Goblin is the only one of them where the spidey villain has a good chance.