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Arana
She fought in the sewers once and wins her fights.

Who do you think wins here?
https://upload.wikimedia.org/wikipedia/en/e/e9/BobAgentofHydra.jpg https://s-media-cache-ak0.pinimg.com/736x/01/a8/f6/01a8f6f98ac093fb44b10a619931a123.jpg

While the Spidergirl in the picture is different from the one you named, it won't matter. Bob would get ran over by Aunt May, much less one of the actual superpowered memberso of the Spiderfamily.

Arana has no powers

Anya got her powers back some years ago.

https://postimg.cc/image/551pe8657/
https://postimg.cc/image/gheaw0u9n/
https://postimg.cc/image/jo8ufnmff/
https://postimg.cc/image/xhx74pmqj/