There are some fantastic documentaries on there. Plus you also get Superman and the Mole Men starring George Reeves as well as all 17 of the 1941 Fleischer cartoons.
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Re: Superman 13 disk set is it worth it ?
I picked up the 13 disc set some time ago and I can confirm that it is definitely worth buying. The extras are just truly remarkable. they will keep you entertained for hours.