i chose mara and luke because mara was imo the only thing that ultimately made EU luke bearable. she gave new meaning to the phrase "she completes me".
I've not read much of the post-RotJ in which Luke and Mara, and Leia and Han are together. Same with Katarn and Jan, though I don't think there's much material including both of them.
Marek and Juno made a good couple for about 20 seconds---then Marek dived in to the Death Star---so they're out.
Revan and Bastila were a cute couple during gameplay, IMO. But that was before they were "together", the cuteness being drawn from the sexual tension and banter.
Sigh... gonna have to say Anakin and Padme. At least from what's seen in AotC, they (or at least the actors) had decent chemistry. Thei scenes on Naboo and the descriptions in the accompanying novel were actually well composed, I felt.
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For sure, just that i never really got into the character hence why i thought she was "boring", the same goes for darth maul and plenty of other characters.
Going by the ones on the list, I'll say Galen and Juno. Galen's feelings for her allowed him to come back to the Light after spending almost his entire life in the Dark Side.