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If The Good Captain can shove his shield down Hercules throat and into his belly he might be able to fill enough space to kill Herc. It'd be more effective than blowing him up.
I think Cap can manage that.

Cap could figure out a strategy to beat Herc, but in a straight up fight with no prep time Herc would KO Cap and head straight to the pay window.

Herc makes cap into his man-slave

this would be like Cap trying to fight an intelligent Hulk with
thousands of years of boxing & wrestling experience....
Hercules wins. Cap just couldn't last for long here.

Captain america doesnt have much of a chance in this, hercules is like above 70 ton strength level right? Hell even if he was only a 20 he could still beat captain america, his fighting skills are amazing arent they (hercules i mean)

I'm gonna miss Captain Americacaptainamerica2 may he rest in pieces...I mean peace..nuke

i see the fight starting out good for Captain America. He'll probably out manuever Herc's strongest attacks and counter....kind of like a boxer.

Eventaully Herc will land a blow and put Cap down.

Imagine what one punch would do.......

http://www.immortalthor.net/thorv2-6.jpg