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Ok I don't know much about Jessica Drew so sorry if this is a bad match up.

They fight in New York city

Come one anyone?

spiderwoman is quite good, she should win....

Ditto

does she have any superhuman reflexes or anything?

Cap's powers of manly seduction for the win!

Captain america will win...

Spider-Woman has Super Powers like strength (something like 7 tons)
is fast, agile and has venom blasts.
And dont forget she is/was a shield agent with lots of combat training.

Hmm now i can remember, she also has the abilitiy to attract man with pheromons or something like that. So she will win because Cap will just look at her breasts while she is hitting him

lol

Didnt she beat Wolverine recently in new avengers?

If she can get one jobber she can get two.

Seriously? Shes above physically with good skills to add and powers. For me she takes this.