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Continuing with my Slayers kick ... which rock-skinned guy prevails?

You'd really need AC/DC's "Hard as a Rock" as background music for this fight.

Hmm if Zelgadis goes toe to toe he will lose. He must use distant magic attacks and even with it is hard to knock out Thing, he has a high durability.

Yeah, probably so. Well ... I could see Astral Vine + a good slash being bad for Thing, but Zel would be a lot wiser not to try it and to use ranged magic instead.