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Not in gameplay but canonically.

Who would be the 5 characters in SF who have demonstrated or have been said to have the most power?

Akuma
Gill
Oro
Bison

And.........................

Ryu probably.

What are some of the things each has done, may I ask?

I've been curious on what Oro and Gill can do.

As far as Street Fighter Akuma goes, he destroyed his island, split Ayers Rock, and kicked a sunken ship out of an ocean.

Gill has/can split a sea, the sky, resurrect himself once a day, and rain small but damaging ice/fire meteors.

Oro with one hand stalemated non-serious Akuma a.k.a Jesus.

Bison...is Bison.

Ryu dodged two bullets EASILY, lifted a heavy ass boulder on both arms, and as Evil Ryu, one-shotted F@gat and can shoot Hadoukens that wreck buildings even.

Edit: Akuma can also skate on water.

Gouki

Oro

Gill

Bison and Ryu(tie IMO)

I'm not sure who gets 5. Lol at GG's Remo joke.