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Batman from the Batman tv show and Spider-Man from the Spectacular Spider-Man tv show switch places and fight each others enemies.

Batman which ones does he defeat and lose to:
Rhino, Sandman, Shocker, Electro, Hammerhead, Tombstone, Green Goblin, Lizard, Vulture, Doc Ock, Venom, Mysterio, Kraven the Hunter

Spider-Man which ones does he defeat and lose to:
Mr. Freeze, The Joker, Firefly, Phosphorus, Bane, Clayface(both of them), Everywhere Man, Gearhead, Joker 2.0, Killer Moth, Killer Croc, Man-Bat, Maxie Zeus, Penguin, The Riddler, Poison Ivy, Ragdoll, Rumor

Batman which ones does he defeat and lose to:
Rhino depends on the BF
Sandman wins
Shocker depends on the BF
Electro wins
Hammerhead looses
Tombstone depends on the BF
Green Goblin depends on the BF
Lizard wins
Vulture looses
Doc Ock depends on the BF
Venom wins
Mysterio looses
Kraven the Hunter looses

Spider-Man which ones does he defeat and lose to:
Mr. Freeze looses
The Joker looses
Firefly looses
Phosphorus ?
Bane looses
Clayface(both of them) wins
Everywhere Man ?
Gearhead ?
Joker 2.0 ?
Killer Moth looses
Killer Croc looses
Man-Bat looses
Maxie Zeus not sure
Penguin looses
The Riddler looses
Poison Ivy depends on the BF
Ragdoll not sure, tend to looses
Rumor ?

EDIT: I've missread your OP my post goes for Comic versions

Originally posted by American Dragon
Batman from the Batman tv show and Spider-Man from the Spectacular Spider-Man tv show switch places and fight each others enemies.

Batman which ones does he defeat and lose to:
Rhino, Sandman, Shocker, Electro, Hammerhead, Tombstone, Green Goblin, Lizard, Vulture, Doc Ock, Venom, Mysterio, Kraven the Hunter

Spider-Man which ones does he defeat and lose to:
Mr. Freeze, The Joker, Firefly, Phosphorus, Bane, Clayface(both of them), Everywhere Man, Gearhead, Joker 2.0, Killer Moth, Killer Croc, Man-Bat, Maxie Zeus, Penguin, The Riddler, Poison Ivy, Ragdoll, Rumor
Batman defeats:
Rhino Shocker Hammerhead, Vulture, Mysterio, Kraven and Ock.
Loses to Venom, Sandman, Electro, Tombstone, Green Goblin, Kraven. That is if we go by KMC standarts, in an actual show he'd find a way to beat most of them.

Spider-man defeats: Freeze, Joker, Firefly, Bane, Everywhere man, Killer Moth, Croc, Man-Bat, Zeus, Penguin, Riddler, Ivy, Ragdoll and thanks to spider sense he'll beat Rumour.
Will lose to: Clayfaces and Joker 2.0 (he was a friggin beast and funny as hell) others I dont remember from the show.
Also again if he was fighting them in a show he'd find a way to beat most of them.