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Colossus is high nigh invulnerable in his armored form.
Can he resist the powers of the Red Skull?

No.

red skull as in with Xavier's mind?

Technically it's a clone of RS, not RS himself.

But I guess it's the only current version there is now, not sure what's happening with Sin.

Piotr loses, he only has basic tp defenses.

If Red Skull was magic, he'd be golden. But as it stands, Colossus is far too vulnerable to mind games.