Jedi Council -
Luke Skywalker - Mastered the arts of using emotion to fuel light side powers and philosophies.
Yoda - Knew that restriction on the Jedi in terms of emotions would help stop a large number of Jedi becoming unbalanced. Had the longest periods of no Dark Jedi arising until Count Dooku (Ie, people like Qel-Droma, Kun, Revan, Malak etc)
Those two would balance each other out and make a perfect order IMO.
Mace Windu - Incredible battlemaster, one of the greatest blademasters in history.
Obi Wan-Kenobi - Respected and balanced, greatest master of Soresu the galaxy ever saw, was a famed negotiator and had a great array of contacts around the galaxy.
Vodo Siosk Baas - Pretty much the same reasons as Yoda.
The Jedi Exile - Balanced, emotional but still restrictive. Never abused her own power but did what had to be done. Was one of the few Jedi who would take down anyone, despite any feelings, for the good of the galaxy. Mastery of Sever Force would help quell any threats.
Nomi Sunrider - Very powerful, great battle meditation that would help quell uprising on planets, or systems. Can settle unrest etc. Chosen more for her abilities to calm the people than her abilities in battle.
Shaak Ti - A balanced and compassionate Jedi, would be a wise leader and a powerful warrior.
Gnost Dural - Historian of the Jedi but still skilled with a blade, would have knowledge that could aid the council should any dangerous threats arise.
Revan - Grey, powerful. Skilled warrior that helps show any Jedi who've lost their way that redemption is possible.
Anakin Skywalker - And how about this time we grant him the rank of master?
Plo Koon - A wise jedi with good political connections, would be a great adviser to the Jedi and a skilled negotiator.