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Who wins the battle?

This is a quick-draw scenario. I'd give it to Electro, since electric bolts travel faster than bullets and Psylocke doesn't have solid defenses against them. However, if she fast enough to use TK before he can send a bolt then she might stand a chance.

is that Electro?

Yeah , Web of Spider-Man #2

Isn't Psylocke a high-level Telepath/Telekinetic? What's stopping her from shielding up then frying his brain?

Psylock stomps tbh

Hmmmm.

Here's Nate Grey Vs Electro.

https://imgur.com/a/avTCJ

no spoilers now! Mwahaha

Got scans of her using the Danger Room with the Sinister Six programmed in?