Black Cat without her bad luck powers is pretty much a non-factor physically and only brings weapons to the table.
I'm pretty sure that Spidey could KO Rogue with a speedblitz at full power, it would take awhile, but I doubt that Rogue could do much to counter once Spidey got it going.
Black Cat would have a much better chance with Gambit in HTH combat becuase of her peak human strength overshadowing Gambit's own athelete-like strength, but she'd have her hands full with Remy once he started throwing his trademark exploding cards. But she could keep him busy long enough for Spidey to get over there and give Gambit a hurtin'.
What Nilla said....
Spidey could take either one-on-one (if you disagree there was a recent SM vs Rogue thread...take up the cause there). And Cat would be a useful distraction. "Bad Luck" powers. Ha! Spider-sense doesn't really make rational sense either but we believe it...but somehow "bad luck" powers just makes me laugh.
Anyway, she looks hot and jumps around while SM takes 'em out.
-DM