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yeah i think its pretty clear that without prep storm would mostlikely win since even if scarlet withc is lucky enough to dodge the first bolt she will have to constantly keep dodging and wont get enough time to work her powers at a more advanced level if she got prep then storm would be dead; in the avengers disassembled finale she killed three avengers destroyed the mansion summoned a bunch of kree battle ships killed agatha karkess and turned she hulk out of controll among a bunch of other things
I think people underestimate Storm too. She has complete control of the weather, so when you fight "her", you actually have to fight Storm the person too. She can move through her own creation. Anyhow, against the Scarlett Witch, i doubt that that would be enough.
Even if Storm is given the advantage from the initiative to hide in a fog, once the fight starts, the witches hex will find its prey.
On one on one, Scarlett Witch pretty much wins. Even when she faces a whole team her power works that same way so as to cause as much improbability as possible.
At normal levels a team would seem sufficient to distract her conjuring, but like i said One on One...ain't gonna happpppen!
Don't forget, this isn't just about Classic Wanda vs. Reality Warping Wanda. There was a "Settled" Wanda who was on the Avengers during Busiek's run. She's generally acknowledged as the second most powerful member of the team, since she achieved mastery over, what was at the time called "Chaos Magic". That version is, in my opinion, more than a match for Storm. She was more or less able to cancel the laws of physics.