I'd say top wills in Marvel are Doom and Strange.
Long already showed why Strange is top tier, so I'll show why Doom is.
Doom (with Galactus' power), in his battle against the Beyonder got his leg torn clean off. He then used an astral projection to ask for help from the heroes. They told him to screw off, so he said "F*** it, I'll do it by myself!!".
Doom continued the fight and quickly lost another limb (his arm). He had lost two limbs, and was getting his ass handed to him on a silver platter, but he STILL kept fighting!! Beyonder got tired of slapping him around and started dissecting his body. Doom (almost half dead) shut out the pain and used his big noggin combined with Galactus' cosmic might to lay Beyonder out flat.
He lost an arm and a leg AND half his body was being dissected but Doom kept coming--and defeated an "unbeatable" foe. If that aint willpower I don't know what is...
"No one rivals Doom! There is no power on Earth, no intellect in all creation, to equal mine!!"