Poll
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Battle of Heroes plays when the buildings go down on Mustafar and Anakin and Obi-Wan are swinging around on ropes and floating on pods.
I personally like Duel of the Fates better. It has a more classic feel, and from a compositional aspect, it has more dramatic undertone. DotF sets itself up better, and plays better with the scene in my opinion. I like BoH, but DotF is one of the classics that makes SW have the best music in film history.