Batman: Mask of the Phantasm. Kevin Conroy is king and Mark Hamil's Joker rocks my world.
Batman Begins (It's all very nice, but credit where credit it due: The Animated Series and Mask of the Phantasm were a cut above.)
The Spidermans. They were both very good, accurate adaptations of the character: I have no criticisms.
Blade II and then Blade. I also liked the Batman flicks and Daredevil and Fantastic Four were but the Superman flicks and Spiderman flicks were all really awful in my opion especially Spiderman since they didn't even get his powers right. I mean any rue spiderman fan knows that Spiderman nevr got the power to shoot webs form getting bit byt the spider. He made a formula that he puts in canisters that attach to his arms and he press a button which releases it through anozzle. Is that so hard for them to hav emtnioned in that move.