Because of the Vibranium used in the creation of Cap's shield, it has the ability to absorb mechanical energy BUT unlike Vibranium, it is virtually indestructible without out some sort of matter manipulator. That's what makes Cap's shield better then Adamantium, it isn't stronger or more durable, just exponentially more useful since it can absorb a near infinite amount of energy. It terms of durability the two are essentially the same.