Janus is right we dont have any clue as to how good Nihilus and Sion is in Lightsaber combat. We can only go by Force capabilities, but even then, Sion has not demonstrated any formidable Force technique aside from him being incapable of getting beaten physically(If that is even a Force Technique instead of it as being just his nature). As for Nihilus we know quite a bit:
Nikkolas has already pointed how Nihilus keeps people(who are supposed to be already dead) alive through sheer will. He was also noted to have created his fleet by tearing it from the mass shadows that surrounded Malachor, using nothing but sheer power.
Im inclined to say that the Sith duo would win because of the above reasons. But because of the fact that we know almost nothing of Sion, he could prove to be the Sith team's undoing. Depending on what level of Force and lightsaber mastery he possess, he could potentially be the weakest link here and could probably slow down Nihilus, which would be dangerous especially against opponents such as Mace who dont need to be stronger in the force to beat somebody.
In the end, Its difficult to truly tell the victors due to lack of information on one side. Basically I apologize for not coming to a conclusion after the rant I just gave above. 😕