Originally posted by chomperx9
i hope you mean the new hawkeye
Not Bullseye Hawkeye but Clint Barton Hawkeye can throw it without being injured or decapitated.
Obviously Cap can use it (Steve or Bucky) and Black Widow may have some extremely limited experience with it. In the JLA/Avengers crossover superman wielded it but only used it to smash things up. Even he remarked how amazing it was.
In Civil War: Fallen Son #3 Hawkeye threw and caught ti perfectly. Tony Stark said that 77 highly trained SHIELD agents had a shot at throwing it. 73 of those are injured in hospital and Stark implied that the other four suffered some form of serious head injury (he jokes about decapitation.)
Although it's also possible that Bullseye could wield it. Clint said throwing the shield was all about "marksmanship" and "accuracy." That's Bullseye's thing.