Why certain Marvel MA's can't use Chi
Lets rationalize why certain top tier MAs don't have the ability to do quasi-mystical chi ampage ala Ironfist, Shang-Chi, Elektra and the Mandarin, yet are still in the same skill ballpark. Drop a of a name and come up with a reason why they can't, and if you have some examples of chi usage or something you think might be chi, from unlikely characters list them as well. DC characters are welcome, but since chi seems to be largely nonexistent (at least visible extensions of it) outside of Shiva's one time only dues-ex machina resurrection technique, I think that will be more difficult.
Captain America: Super Soldier Serum. Having his body augmented by outside sources likely buts Steve at a disadvantage. Hard for your mind and body to be one, when your body isn't even technically yours. Although, Steve has demonstrated at the very least a fundamental knowledge of Chi and was teaching Peter Parker to focus/harness it, he doesn't seem to have any practical uses for it.
Black Panther: Heart Shaped Herb? The superhuman enhancements from the Herb likely put T'Challa in the same boat as Steve Rogers.
Wolverine: The same reason he can't access the Alshra unaided. Wolverine is fundamentally at odds with himself on virtually every level. His mind is at odds with his body and his healing factor is at odds with his Adamantium skeleton. He will never achieve the necessary harmony needed to access the the Alshra or harness his chi in any substantial way.
Daredevil: While his radar sense was originally a side affect of being blinded by radio active waste, he lost that ability. The radar sense he has now he was taught by Stick which is an extension of skill and arguably a chi ability.
Taskmaster: Has shown some chi ampage in the passed. He has demonstrated an "iron-fist" technique that will stop a mans heart with one blow which was attributed to chi. I would also attribute his ability to briefly boost his speed to the levels need to catch bullets and blitz a bullet timer as a chi ability, but that was never stated.