Green Arrow vs Spider-Man

Two fights, no help, no prep nor prior knowledge of one another.
Both mistake one another for a villain.

1. Urban setting (such as downtown Chicago)
2. Open grassy field (something like you'd find in South Dakota)

Normal Spidey and Normal Ollie

No Symbiote and No Phantom Zone arrows

Spidey pwns!

Parker.

Spidey.

Pete stomps. It doesn't matter how good of a shot you are when your opponent is several times too fast to be hit with a flying arrow.

Add to that, Pete's webbing (which Ollie won't be able to dodge), and the fact that Pete can one-shot him.

Pete for both. The webbing would phuck G.A right up at a distance, and with his speed, spidey is most likely to hit first..