Shaw is pretty much unstoppable in this scenario. Maybe Spidey can web him up to immobilize him? Would that work? I'm not sure. He would be pushing and struggling against the webs, and they would be pushing back with the same force, which he would absorb and get stronger off of, if my impression of his powers are right. That means he cant really be hurt or stopped here. It basically comes down to Shaw, and he is above everyone here.