Stats wise this is very even. Spiderwomen have a very slight speed advantage made up for by an equally light durability advantage to hawk and Dove.
I'm going with team Marvel ONLY because of
1. Hank Hall's demeanor. he'll charge in and underestimate the women due to his sexism.
2. Don hall's genuine gentlemanly regard for Women. he wont attack until it's likely too late.
So the spider women have to down to 2v4 pretty quick