The decapitations of Dooku and Sirak primarily as how they serve as transformative moments for the decapitators. Sirak secondarily because the decapitator was Bane and because of the line "Those who beg for mercy are too weak to deserve it." Dooku secondarily because of the line "DEW IT" and because of the derpy face Anakin makes while he's doing it.
The decapitation of Pre Vizsla as well primarily because it demonstrates Pre Vizsla's honor and gives the character the closure of getting decapitated by Maul and the very same blade that would go on to kill Dutchess Satine. Secondarily because Maul is a badass and his takeover of Mandalore was where he peaked in TCW.