Blade is faster and more skilled but Tobey is the strongest and most durable Spidey to date. This is a guy who withstood being pounded repeatedly by hundreds of tons of sand and took a pumpkin bomb to the face. Blade cant damage him enough here.
Spidey should also take the second round as long as he keeps a safe distance away. Blade is a guy who won a sword fight with a man who cut bullets out of the air. If Spidey got in close he'd be minced, but thankfully both sides have their equipment which means Spidey just webs him up and beats his face in.
A better match would have been Hollands Spidey i think, though the second round would probably still result in a web up.