Spider-man Psi vs. Venom greater web strength
Can Spider-man calculate a web to match a psi web woven by Spider-women and have it turn out good enough to hold back an extra 100 and 50 tons like Spider Women held Rogue and Colossus for a few moments?
I think he can.
As he had some social anxiety he has learned to get over he can make an educated guess about the personalities of those he fights and draw his webs like Spider-women psi's webs based on the enemy's id and personalize his webs design.
If he distracts the enemy no matter who he is fighting with a joke while he casts his own web even Madame Web might be safe with his extra strength.