Captain Jack Sparrow at the very top of my list...
And I might bluntly add the only film that Kiera Knightly would viable in is a porn. What is with her constantly trying to appear sexy, flirting with the camera, obviously trying to turn on the audience, and posing in every single poster like a stripper gone clothed? Not to mention she's a cheesy actor.
For God's sake, Kiera, it's a Disney.
-doc holiday(val kilmer, tombstone)
-captain jack sparrow, a VERY close second(johnny sexiness depp, pirates of the caribbean: the curse of the black pearl)
-merry and pippin, you cant have one without the other(dominic monahan and billy boyd, the lord of the rings series)
-wolverine(hugh jackman my LOVER, x men and x2: xmen united)
-legolas and gimli, sooooo funny together(orlando bloom a god among men and john rhys davies, the lord of the rings series)