welll i would say that if this is classic psylock then she is not going to win this fight as alll she has on her side is her telepathy and some body armor to fall back on
i allways thought that her martial art and physicic knifes where from the post sige perellus ( bad spelling) phylocke and not the classic vertion we are talking about who was not confident about her martial arts skills and had to wear armor... i also dont remember he doing any decent phycic feats other then wiping the memories of crowds.
Martial arts skill isn't going to make up for vastly inferior strength, reflexes and speed. Let's face it folks, Sabretooth could take her and he's below Spider Woman in pretty much every department.
In Spider Woman: Origin we learned that she was trained by taskmaster and was one of the most skilled students he had ever had. She beat him a couple of times even, not a lot of people has that to back them up.