Batman is peak human in most respects (save agility), Cap is peak in most but he is enhanced past peak in a few areas (like strength), Black Panther is also enhanced past peak in some areas (like agility) and DD is peak all across the charts.
DD is the pinicle of peak human IMO. He is Batman + Nightwing in one bundle while Cap and DD are above him or even with him in every way the have been enhaced by the SSS and magic herbs.
Skill goes to Cap or DD.