spider-man in gotham faces:
Well Batman's rogue's gallery tends to be more cerebral and use nastier means in population and such. That being said most if not all of them are severely lacking physically compared to others. So then I'll give it a prep take, and a straight up fight
-joker 3/10, 10/10
-freeze 7/10 , 3/10
-bane 10/10, 10/10
-shiva 10/10, 8/10
-ra's-al-ghul 2/10, 10/10
-clay face 10/10, 0/10
-kgbeast 10/10, 10/10
-prometheus 4-5/10, 8/10
-man-bat 10/10, 10/10
-poison ivy 3-4/10, 0/10
batman in manhattan faces:
Spider-man's rogues tend to be a lot more physical, and a lot more straight up brutal. Some of them possessing better standard tech then
Batman himself. On the same token they tend to be less skilled fighters, and more easy to manipulate.
-lizard 10/10, 2-3/10
-carnage 7/10, 0/10
-rhino 10/10, 2-3/10
-doc ock 6-7/10, 1-2/10
-hydro-man 10/10, 0/10
-sandman 10/10, 0/10
-electro 6/10, 1-2/10
-green goblin 7/10, 2/10
-kraven the hunter 8-9/10, 4/10
-mysterio 8/10, 10/10
OK then my final verdict on the subject is this:
Is that Spiderman generally does better in straight up random scenarios, while Batman does better in prep ones. Now people tend to forget that Spiderman isn't stupid and has done various smart things many times.
On the other hand Batman while yes generally does take on people way out of his weight class, most heroes do, he generally does it through prep or previous knowledge of the person. On the other hand we have seen where, when faced with overwhelming physical superiority, he has been beaten down. Slade becomes a perfect image of this.