He thinks Luke is their only hope because Leia was of no use to them. Her hatred for the emperor and for Vader would have completely undermined Yodas and Ob1's plans from the beginning they would have lost yet another Jedi to the Dark Side. And once the empire and Vader had one of Vader’s offspring in their control it would be too late for the rebellion and any chance of the Jedi making any kind of come back in the galaxy. Leia was weak. Luke was raised basically away from the empire and under the radar of the emperor.